物质信息
ID:719211
名称和标识
IUPAC标准名
octadecafluoro-decahydronaphthalene
IUPAC传统名
perfluorodecalin
别名
Octadecafluoro(decahydronaphthalene)OctadecafluorodecalinPerfluoro(decahydronaphthalene), cis + trans全氟(十氢化萘),顺式+反式
化合物性质
理化性质
沸点
141-142°C
熔点
-10 to -7°C
密度
1.940
折射率
1.3145
安全信息
RTECS编号
QJ3175000
TSCA收录
是
产品相关信息
纯度
95%
描述信息
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分子图谱
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参考文献
• The ability of perfluorinated solvents to solubilize gases, together with their unique phase properties, have been exploited in a system for oxidation of aldehydes to acids, sulfides to sulfoxides and sulfones, and alkenes to epoxides. The reactions are carried out in the presence of dissolved O2, using a transition metal (Ru, Ni) catalyst with perfluorinated ligands, in a perfluoro(decahydronaphthalene)/toluene solvent mixture under monophasic conditions at 64oC. On cooling, phase separation takes place, enabling the product to be isolated from the toluene phase, and the catalyst system to be recycled in the fluorous phase: Angew. Chem. Int. Ed., 36, 1454 (1997).