物质信息
ID:717609
名称和标识
IUPAC标准名
propane-1,3-dithiol
IUPAC传统名
1,3-propanedithiol
别名
1,3-Propanedithiol1,3-丙二硫醇Trimethylene mercaptan
化合物性质
安全信息
欧盟危险性物质标志
刺激性 (Xi)联合国危险货物编号
UN3334
GHS危险声明
H315-H319-H335-H227
危险公开号
36/37/38
TSCA收录
是
RTECS编号
TZ2585500
GHS危险品标识
急性毒性（口服，皮肤接触，吸入），类别4
皮肤刺激，类别2
眼刺激，类别2
皮肤过敏，类别1
特定目标器官毒性 -一次接触，类别3
GHS警示性声明
P210-P305+P351+P338-P302+P352-P321-P405-P501A
安全公开号
23-26-37-60
联合国危险货物等级
9
理化性质
沸点
168-170°C
折射率
1.5400
熔点
-79°C
溶解度
Slightly soluble in water. Miscible with alcohol, ether, chloroform, ether
密度
1.077
闪点
63°C(145°F)
产品相关信息
纯度
97%
描述信息
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分子图谱
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参考文献
• Precursor of cyclic dithioacetal (1,3-dithiane) derivatives of carbonyl compounds. The protection step is catalyzed by Lewis acids, e.g. BF3 etherate: Tetrahedron Lett., 871 (1971), TiCl4: Tetrahedron Lett., 24, 1289 (1983), Aluminum trifluoromethanesulfonate, B20785, or Indium(III) trifluoromethanesulfonate, 40131. Diothioacetalization can be accomplished under neutral, solvent-free conditions using Lithium trifluoromethanesulfonate, 39322, as catalyst: Tetrahedron Lett., 40, 4055 (1999). For the preparation of monocyclic dithioacetals of ?-diketones at low temperature in the presence of BF3 etherate, see: Tetrahedron, 44, 2283 (1988).
• For deprotection methods and uses of 1,3-dithianes as acyl anion equivalents, see: 1,3-Dithiane, A10505.
• Alternatively, 1,3-dithianes can be prepared by alkylation with reactive gem-dihalides under phase-transfer conditions: Liebigs Ann. Chem., 1589 (1982).