物质信息
ID:714377
名称和标识
IUPAC标准名
ammonium cyanosulfanide
别名
Ammonium rhodanideAmmonium thiocyanate硫氰酸铵
IUPAC传统名
ammonium thiocyanate
化合物性质
产品相关信息
纯度
98+%
安全信息
GHS危险品标识
急性毒性（口服，皮肤接触，吸入），类别1,2,3
TSCA收录
是
保存注意事项
Light Sensitive & Hygroscopic
GHS警示性声明
P261-P280-P361-P302+P352-P405-P501A
欧盟危险性物质标志
有害性 (X)安全公开号
13-36/37-46-61
危险公开号
20/21/22-32-52/53
RTECS编号
XK7875000
GHS危险声明
H311-H302-H332-H402-H412
理化性质
密度
1.305
熔点
147-149°C
描述信息
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分子图谱
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参考文献
• In combination with CAN in t-butanol, epoxides are converted to thiiranes in high yield: Synthesis, 821 (1996). The same conversion can also be effected in the presence of SbCl3 in acetonitrile: Indian J. Chem., 38B, 605 (1999). CAN also promotes the direct conversion of activated aryl systems, e.g. indoles, pyrroles and N,N-dialkylanilines to aryl thiocyanates: Tetrahedron Lett., 40, 1195 (1999).
• Thiocyanogen bromide can be generated in situ by reaction with bromine in acetic acid, e.g. in the thiocyanation of N,N-dimethylaniline to 4-N,N-dimethylaminophenylisothiocyanate: Org. Synth. Coll., 2, 574 (1943).
• Also useful for the conversion of arylamines to thioureas either indirectly via benzoyl isothiocyanate: Org. Synth. Coll., 3, 735 (1955), or directly, but in lower yield, by reaction of ammonium thiocyanate with the amine in the presence of HCl: Org. Synth. Coll., 4, 180 (1963).