物质信息
ID:449777
名称和标识
IUPAC标准名
(1R,2R,5S,8S,9S,10R,11R,12S)-5,12-dihydroxy-11-methyl-6-methylidene-16-oxo-15-oxapentacyclo[9.3.2.15,8.01,10.02,8]heptadec-13-ene-9-carboxylic acid
别名
GibrescolBerelexGibberellin A3GA3GibrofitActivolGibberellic acid
IUPAC传统名
(1R,2R,5S,8S,9S,10R,11R,12S)-5,12-dihydroxy-11-methyl-6-methylidene-16-oxo-15-oxapentacyclo[9.3.2.15,8.01,10.02,8]heptadec-13-ene-9-carboxylic acid
数据登录号
CAS号
化合物性质
产品相关信息
应用领域
Plant growth regulator
Used in malting of barley
Used as an experimental research mutagen
生物来源
Produced by Gibberella fujikuroi and present in higher plants
药理学性质
生物活性机理
Stimulates the cells of germinating seeds to produce mRNA molecules that code for hydrolytic enzymes
Plant growth factor.
描述信息
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分子图谱
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参考文献
• Verbiscar, A.J. et al., Phytochemistry, 1967, 7, 807, (biosynth)
• Cross, B.E. et al., Chem. Comm., 1965, 535, (biosynth)
• Yamaguchi, I. et al., Agric. Biol. Chem., 1970, 34, 1439, (deriv)
• McCapra, F. et al., J.C.S.(C), 1966, 1577, (cryst struct)
• Schreiber, K. et al., Phytochemistry, 1966, 5, 1221, (isol)
• Aldrich Library of 13C and 1H FT NMR Spectra, 1992, 1, 1145B, (nmr)
• Aldrich Library of FT-IR Spectra, 1st edn., 1985, 1, 703A, (ir)
• Yokota, T. et al., Agric. Biol. Chem., 1971, 35, 583, (isol)
• Schwartz, E. et al., Pharmazie, 1983, 38, 716, (pharmacol)
• Pesticide Manual, 9th edn., 1991, No. 6910
• Danheiser, R.L., Strategies Tactics Org. Synth., 1984, 21; CA, 102, 6856, (book)
• Sheng, C. et al., Biosci., Biotechnol., Biochem., 1992, 56, 564, (isol, GA85)
• Kutschabsky, L. et al., J.C.S. Perkin 1, 1983, 1653, (cryst struct)
• Blake, P.S. et al., Phytochemistry, 1993, 32, 781, (GA87)
• Lewis, R.J., Sax's Dangerous Properties of Industrial Materials, 8th edn., Van Nostrand Reinhold, 1992, GEM000
• Hook, J.N. et al., J.O.C., 1984, 49, 3250, (synth)
• Hook, J.M. et al., J.A.C.S., 1980, 102, 6628, (synth)
• Al-Ekabi, H.K. et al., Can. J. Chem., 1984, 62, 1996, (ms)
• Bhaskar, K.V. et al., Tet. Lett., 1991, 32, 6203, (GA85, GA86)
• Agrochemicals Handbook, 3rd edn., Royal Society of Chemistry, 1992, A797
• Synform, 1984, 2, 197, (rev)
• Dawson, R.M. et al., Phytochemistry, 1975, 14, 2593, (biosynth)
• Corey, E.J. et al., J.A.C.S., 1982, 104, 6129, (synth)
• Lewer, P. et al., Phytochemistry, 1984, 23, 2803, (biosynth)
• Hossain, M.B. et al., Acta Cryst. C, 1988, 44, 1022, (cryst struct)