物质信息
ID:365560
名称和标识
IUPAC标准名
{1-[2-(diphenylphosphanyl)naphthalen-1-yl]naphthalen-2-yl}diphenylphosphane
IUPAC传统名
binap
别名
(S)-(-)-(1,1′-Binaphthalene-2,2′-diyl)bis(diphenylphosphine)(S)-(-)-BINAP(S)-(-)-1,1′-联萘-2,2'-双二苯膦(S)-(-)-2,2′-双(二苯膦基)-1,1′-联萘(S)-(-)-2,2′-Bis(diphenylphosphino)-1,1′-binaphthalene
化合物性质
产品相关信息
光学纯度
enantiomeric ratio: ≥99.5:0.5 (HPLC)
级别
puriss.
线性分子式
[(C6H5)2PC10H6-]2
理化性质
熔点
238-242 °C (dec.)
238-240 °C(lit.)
比旋光度
[α]20/D -239±5°, c = 0.3% in toluene
安全信息
描述信息
Application
Reactant involved in:
• Enantioselective and diastereoselective unpoled carbonyl allylation1
• Syntehsis of organophophine oxides as anittumor agents2
• SN2 halogenation of hydroxy groups3
• Synthesis of BINAP complexes4,5
• Studies of conformational flexibility of BINAP chelates6
Reactant involved in:
• Enantioselective and diastereoselective unpoled carbonyl allylation1
• Syntehsis of organophophine oxides as anittumor agents2
• SN2 halogenation of hydroxy groups3
• Synthesis of BINAP complexes4,5
• Studies of conformational flexibility of BINAP chelates6
分子图谱
暂无数据
点击上传数据
参考文献
暂无数据
点击上传数据