物质信息
ID:356400
名称和标识
IUPAC标准名
ethyl 2-(diethoxyphosphoryl)-2-fluoroacetate
IUPAC传统名
ethyl 2-(diethoxyphosphoryl)-2-fluoroacetate
别名
2-Fluoro-2-phosphonoacetic acid triethyl ester2-氟-2-膦酰基乙酸三乙酯Ethyl diethylphosphonofluoroacetateTriethyl 2-fluoro-2-phosphonoacetateDiethyl [(ethoxycarbonyl)fluoromethyl]phosphonate
化合物性质
理化性质
沸点
75 °C/0.01 mmHg(lit.)
闪点
163.4 °F
73 °C
折射率
n20/D 1.425(lit.)
n20/D 1.625
密度
1.194 g/mL at 25 °C(lit.)
安全信息
GHS危险品标识
急性毒性（口服，皮肤接触，吸入），类别4
皮肤刺激，类别2
眼刺激，类别2
皮肤过敏，类别1
特定目标器官毒性 -一次接触，类别3
GHS警示词
Warning
GHS危险声明
H315-H319-H335
GHS警示性声明
P261-P305+P351+P338
危险公开号
36/37/38
MSDS下载
安全公开号
26-36
欧盟危险性物质标志
刺激性 (Xi)个人保护装置
Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
德国WGK号
3
产品相关信息
级别
technical
纯度
≥96% (GC)
线性分子式
(C2H5O)2P(O)CH(F)CO2C2H5
描述信息
Other Notes
Horner-Wittig 试剂，用于合成 α-氟-α,β-不饱和酯8,9,10
Application
Reactant for:
• Diels-Alder reactions1
• Biosynthesis of terpene2
• Stereoselective synthesis of unsaturated esters, fluorides and nitriles from the reactions of aldehydes and ketones using Wadsworth-Emmons phosphonates3
• Synthesis of quinolones4
• Horner-Wadsworth-Emmons asymmetric hydration5
• Addition reactions and the subsequent application to click chemistry6
• Asymmetric intermolecular Stetter reactions7
Horner-Wittig 试剂，用于合成 α-氟-α,β-不饱和酯8,9,10
Application
Reactant for:
• Diels-Alder reactions1
• Biosynthesis of terpene2
• Stereoselective synthesis of unsaturated esters, fluorides and nitriles from the reactions of aldehydes and ketones using Wadsworth-Emmons phosphonates3
• Synthesis of quinolones4
• Horner-Wadsworth-Emmons asymmetric hydration5
• Addition reactions and the subsequent application to click chemistry6
• Asymmetric intermolecular Stetter reactions7
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参考文献
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