物质信息

ID:327113

N-甲氧基-N-甲羰基甲基膦酸二乙酯

名称和标识
IUPAC标准名
diethyl {[methoxy(methyl)carbamoyl]methyl}phosphonate
IUPAC传统名
diethyl [methoxy(methyl)carbamoyl]methylphosphonate
别名
Diethyl (N-methoxy-N-methylcarbamoylmethyl)phosphonateN-甲氧基-N-甲羰基甲基膦酸二乙酯N-Methoxy-N-methyl-phosphonoacetamide diethyl esterDiethyl N-methoxy-N-methylphosphonoacetamideN-Methoxy-N-methyl-2-(diethyl phosphono)acetamideDiethylphosphonoacetic acid N-methyl-N-methoxyamide
数据登录号
Beilstein号
PubChem SID
化合物性质
产品相关信息
纯度
96%
线性分子式
CH3ON(CH3)COCH2P(O)(OC2H5)2
理化性质
闪点
230 °F
110 °C
密度
1.163 g/mL at 25 °C(lit.)
折射率
n20/D 1.455(lit.)
沸点
90 °C/17 mmHg(lit.)
安全信息
欧盟危险性物质标志
刺激性 刺激性 (Xi)
MSDS下载
安全公开号
26-36
GHS危险品标识
GHS07
急性毒性(口服,皮肤接触,吸入),类别4
皮肤刺激,类别2
眼刺激,类别2
皮肤过敏,类别1
特定目标器官毒性 -一次接触,类别3
GHS警示词
Warning
GHS危险声明
H315-H319-H335
德国WGK号
3
危险公开号
36/37/38
个人保护装置
Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS警示性声明
P261-P305+P351+P338
描述信息
Application
Wittig 羰基化试剂7
Reactant for:
• Preparation of ring-expanded bryostatin analogs as antitumor agents1
• Asymmertic synthesis of pinnatoxins A and G via diastereoselective Ireland-Claisen rearrangement, ring closing metathesis, and cyclization2
• Rh2(II)-catalyzed nitro-group migration reactions3
• Stereoselective synthesis of cyclohexanones via phase transfer catalyzed double addition reactions4
• Stereoselective synthesis of (+)-polyrhacitide A via aldol reaction, Horner-Wardsworth-Emmons reaction, Evans acetal intramolecular oxa-Michael reaction and diastereoselective syn reduction reaction as the key steps5
• Preparation of substituted furans via olefin cross-metathesis6
包装
1, 5 g in glass bottle
分子图谱
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参考文献
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