物质信息
ID:326287
名称和标识
别名
TADDOL1,1,4,4-四苯基-2,3-O-异亚丙基-L-苏糖醇(4R,5R)-2,2-二甲基-α,α,α′,α′-四苯基-1,3-二氧戊环-4,5-二甲醇(4R,5R)-4,5-双(二苯基羟甲基)-2,2-二甲基二氧戊环(4R,5R)-2,2-Dimethyl-α,α,α′,α′-tetraphenyldioxolane-4,5-dimethanol(-)-2,3-O-Isopropylidene-1,1,4,4-tetraphenyl-L-threitol1,1,4,4-Tetraphenyl-2,3-O-isopropylidene-L-threitol(4R,5R)-4,5-Bis(diphenylhydroxymethyl)-2,2-dimethyldioxolane(-)-反式-α,α′-(2,2-二甲基-1,3-二氧戊环-4,5-二基)双(二苯基甲醇)(-)-2,3-O-异亚丙基-1,1,4,4-四苯基-L-苏糖醇(-)-trans-α,α′-(2,2-Dimethyl-1,3-dioxolane-4,5-diyl)bis(diphenylmethanol)
IUPAC标准名
[(4R,5R)-5-(hydroxydiphenylmethyl)-2,2-dimethyl-1,3-dioxolan-4-yl]diphenylmethanol
IUPAC传统名
[(4R,5R)-5-(hydroxydiphenylmethyl)-2,2-dimethyl-1,3-dioxolan-4-yl]diphenylmethanol
化合物性质
安全信息
理化性质
比旋光度
[α]19/D -62.6°, c = 1 in chloroform
熔点
193-195 °C(lit.)
产品相关信息
纯度
97%
Empirical Formula (Hill Notation)
C31H30O4
描述信息
包装
1 g in glass bottle
Application
Hydrogen-bonding organocatalyst examined in terms of acidity, deprotonation enthalpies and hydrogen bonding1Catalyst involved in synthesis of cyclopropylamines via addition reactions of Grignard reagents to amides2Reactant or reagent involved in:
• Enantioswitching of catalytic asymmetric hydroboration3
• Synthesis of derivative ligands for asymmetric hydroformylation of alkenes4
• Amide-directed catalytic asymmetric hydroboration of trisubstituted alkenes5
• Addition of deactivated alkyl Grignard reagents to aldehydes6
1 g in glass bottle
Application
Hydrogen-bonding organocatalyst examined in terms of acidity, deprotonation enthalpies and hydrogen bonding1Catalyst involved in synthesis of cyclopropylamines via addition reactions of Grignard reagents to amides2Reactant or reagent involved in:
• Enantioswitching of catalytic asymmetric hydroboration3
• Synthesis of derivative ligands for asymmetric hydroformylation of alkenes4
• Amide-directed catalytic asymmetric hydroboration of trisubstituted alkenes5
• Addition of deactivated alkyl Grignard reagents to aldehydes6
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