物质信息
ID:316327
名称和标识
IUPAC传统名
tris(4-chlorophenyl)phosphane
IUPAC标准名
tris(4-chlorophenyl)phosphane
别名
三(4-氯苯基)膦Tris(4-chlorophenyl)phosphineNSC 136459Tris(p-chlorophenyl)phosphine
化合物性质
安全信息
危险公开号
36/37/38
个人保护装置
dust mask type N95 (US), Eyeshields, Gloves
GHS警示性声明
P261-P305+P351+P338
GHS危险品标识
急性毒性（口服，皮肤接触，吸入），类别4
皮肤刺激，类别2
眼刺激，类别2
皮肤过敏，类别1
特定目标器官毒性 -一次接触，类别3
安全公开号
26-37/39
GHS危险声明
H315-H319-H335
德国WGK号
3
MSDS下载
欧盟危险性物质标志
刺激性 (Xi)GHS警示词
Warning
理化性质
熔点
100-103 °C(lit.)
产品相关信息
纯度
95%
线性分子式
(ClC6H4)3P
描述信息
包装
1 g in glass bottle
Application
Catalyst for:
• Preparation of chromans and (E,E)-1,3-dienes via reaction of γ-substituted allenoates with aldehydes1
• Solvent-free Heck reactions2Cocatalyst in:
• Regioselective carbomagnesiation of terminal alkynes and enynes with alkyl Grignard reagents3
• Rhodium-catalyzed coordination-assisted regioselective alkenylation of aromatic C-H bonds with terminal silylacetylenes4
• Rhodium-catalyzed hydrogenation reactions5
• Platinum-catalyzed allylation reactions6
1 g in glass bottle
Application
Catalyst for:
• Preparation of chromans and (E,E)-1,3-dienes via reaction of γ-substituted allenoates with aldehydes1
• Solvent-free Heck reactions2Cocatalyst in:
• Regioselective carbomagnesiation of terminal alkynes and enynes with alkyl Grignard reagents3
• Rhodium-catalyzed coordination-assisted regioselective alkenylation of aromatic C-H bonds with terminal silylacetylenes4
• Rhodium-catalyzed hydrogenation reactions5
• Platinum-catalyzed allylation reactions6
分子图谱
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参考文献
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