物质信息
ID:306549
名称和标识
IUPAC标准名
13-(2-{13-phosphapentacyclo[13.8.0.02,11.03,8.018,23]tricosa-1(23),2,4,6,8,10,15,17,19,21-decaen-13-yl}phenyl)-13-phosphapentacyclo[13.8.0.02,11.03,8.018,23]tricosa-1(15),2,4,6,8,10,16,18,20,22-decaene
别名
(R,R)-1,2-Bis[(R)-4,5-dihydro-3H-binaphtho(1,2-c:2′,1′-e)phosphepino]benzene(R)-BINAPHANE(R,R)-1,2-二[(R)-4,5-二氢-3H-联萘并(1,2-c:2′,1′-e)磷杂庚英并]苯(R)-联萘
IUPAC传统名
13-(2-{13-phosphapentacyclo[13.8.0.02,11.03,8.018,23]tricosa-1(23),2,4,6,8,10,15,17,19,21-decaen-13-yl}phenyl)-13-phosphapentacyclo[13.8.0.02,11.03,8.018,23]tricosa-1(15),2,4,6,8,10,16,18,20,22-decaene
化合物性质
安全信息
理化性质
熔点
>200 °C (dec.)
产品相关信息
Empirical Formula (Hill Notation)
C50H36P2
描述信息
Application
(R)-联萘具有优异的对映选择性（光学纯度高达 99% 以上），用于氢化 β-取代芳基烯酰胺的 E/Z-同分异构混合物。6
Chiral Quest Phosphine Ligands for Asymmetric HydrogenationCatalyst involved in:
• Enantioselective anilinosulfonamide allyl alcohol cyclization1
• Synthesis of β-trifluoromethyl α-amino acids2
• Phosphine-catalyzed cycloadditions of aldehydes and ketoketenes3
• Dimerization of ketoketenes4
• Enantioselective carbonyl-ene reactions via palladium and platinum derivatives5
(R)-联萘具有优异的对映选择性（光学纯度高达 99% 以上），用于氢化 β-取代芳基烯酰胺的 E/Z-同分异构混合物。6
Chiral Quest Phosphine Ligands for Asymmetric HydrogenationCatalyst involved in:
• Enantioselective anilinosulfonamide allyl alcohol cyclization1
• Synthesis of β-trifluoromethyl α-amino acids2
• Phosphine-catalyzed cycloadditions of aldehydes and ketoketenes3
• Dimerization of ketoketenes4
• Enantioselective carbonyl-ene reactions via palladium and platinum derivatives5
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