Substance
ID:745700
Names and Identifiers
IUPAC Traditional name
chloroform tris(dibenzylideneacetone) dipalladium
IUPAC name
tris((1E,4E)-1,5-diphenylpenta-1,4-dien-3-one) trichloromethane dipalladium
Synonyms
三(二亚苄基茚丙酮)二钯(0)氯仿加合物Tris(dibenzylideneacetone)dipalladium(0) chloroform adductDipalladiumtris(dibenzylideneacetone) chloroform adduct
Properties
Safety Information
TSCA Listed
否
European Hazard Symbols
Harmful (X)GHS Precautionary statements
P260-P281-P301+P310-P321-P405-P501A
GHS Pictograms
Respiratory sensitization, category 1
Germ cell mutagenicity, categories 1A,1B,2
Carcinogenicity, categories 1A,1B,2
Reproductive toxicity, categories 1A,1B,2
Specific Target Organ Toxicity – Single exposure, categories 1,2
Specific Target Organ Toxicity – Repeated exposure, categories 1,2
Aspiration Hazard, category 1
Acute toxicity (oral, dermal, inhalation), categories 1,2,3
Risk Statements
22-40-48/20/22
Safety Statements
36/37
GHS Hazard statements
H301-H351-H373
Product Information
Purity
98%
Physical Property
Melting Point
131-135°C
Molecule Details
No Data Available
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Molecular Spectra
No Data Available
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References
• Phosphine-free Pd(0) catalyst. Catalyzes the addition of arylboronic acids to aldehydes, affording secondary alcohols. No reaction was observed in the absence of chloroform: Org. Lett., 7, 4153 (2005).