Substance

ID:743526

tert-Butyl alcohol, anhydrous

Names and Identifiers
IUPAC Traditional name
2-methyl-2-propanol
IUPAC name
2-methylpropan-2-ol
Synonyms
2-Methyl-2-propanoltert-Butanol叔丁醇, 无水tert-Butyl alcohol, anhydrous
Registration numbers
MDL Number
CAS Number
EC Number
Beilstein Number
Merck Index
Properties
Physical Property
Refractive Index
1.3870
Apperance
Liquid
Flash Point
11°C(52°F)
Melting Point
25°C
Density
0.786
Boiling Point
83°C
Safety Information
GHS Pictograms
GHS02
Flammable gases, category 1
Flammable aerosols, categories 1,2
Flammable liquids, categories 1,2,3
Self-reactive substances and mixtures, Types B,C,D,E,F
Pyrophoric liquids, category 1
Pyrophoric solids, category 1
Self-heating substances and mixtures
Substances and mixtures, which in contact with water, emit flammable gases, categories 1,2,3
Organic peroxides, Types B,C,D,E,F
GHS07
Acute toxicity (oral, dermal, inhalation), category 4
Skin irritation, category 2
Eye irritation, category 2
Skin sensitisation, category 1
Specific Target Organ Toxicity – Single exposure, category 3
GHS Precautionary statements
P210-P241-P303+P361+P353-P305+P351+P338-P405-P501A
RTECS
EO1925000
European Hazard Symbols
Harmful Harmful (X)
Flammable Flammable (F)
Packing Group
II
TSCA Listed
Hazard Class
3
Risk Statements
11-20-36/37
Safety Statements
9-16-46
UN Number
UN1120
GHS Hazard statements
H225-H332-H319-H335
Product Information
Packaging
packaged under Argon in resealable ChemSeal? bottles
Purity
99.5%
Molecule Details
No Data Available
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Molecular Spectra
No Data Available
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References
• For preparation of the Li salt and reaction with an acid chloride as an example of a method for esterification of hindered alcohols, see: Org. Synth. Coll., 6, 259 (1988). A general method for esterification of carboxylic acids using DCC and DMAP is illustrated for t-butyl ethyl fumarate: Org. Synth. Coll., 7, 93 (1990). For use of the same combination for the preparation of t-butyl esters of N-protected amino acids, see: Org. Prep. Proced. Int., 20, 180 (1988). See also Appendix 6.