Substance
ID:743471
Names and Identifiers
IUPAC name
lithium(1+) ion iodide
IUPAC Traditional name
lithium(1+) ion iodide
Synonyms
Lithium iodide, anhydrous碘化锂,无水
Properties
Safety Information
GHS Pictograms
Acute toxicity (oral, dermal, inhalation), category 4
Skin irritation, category 2
Eye irritation, category 2
Skin sensitisation, category 1
Specific Target Organ Toxicity – Single exposure, category 3
Safety Statements
26-37
TSCA Listed
是
Risk Statements
36/38
European Hazard Symbols
Irritant (Xi)Storage Warning
Light Sensitive & Hygroscopic
GHS Hazard statements
H315-H319
GHS Precautionary statements
P280-P305+P351+P338-P302+P352-P321-P362-P332+P313
Product Information
Purity
98+%
Physical Property
Refractive Index
1.955
Apperance
Lumps/powder, Ampouled under argon
Solubility
Soluble in water, alcohol, acetone and methanol. Very soluble in NH4OH
Boiling Point
1170-1190°C
Density
4.076
Melting Point
449°C
Molecule Details
No Data Available
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Molecular Spectra
No Data Available
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References
• Can be used in refluxing pyridine or collidine for selective cleavage of methyl esters: Rocz. Chem., 30, 323 (1956); Helv. Chim. Acta, 43, 113 (1960). For review and comparison with other methods, see: Org. React., 24, 187 (1976).
• Also cleaves aralkyl ethers in collidine: Chem. Commun., 616 (1969); J. Am. Chem. Soc., 103, 4247 (1981).
• For rearrangement of oxaspiropentane to cyclobutanone with LiI, see: Org. Synth. Coll., 6, 320 (1988).