Substance
ID:742323
Names and Identifiers
IUPAC name
iodochlorane
IUPAC Traditional name
iodine monochloride
Synonyms
ChloroiodideIodine monochloride单氯化碘
Registration numbers
CAS Number
EC Number
MDL Number
Merck Index
Beilstein Number
Properties
Physical Property
Apperance
Crystalline/Liquid
Boiling Point
96-98°C
Melting Point
25-27°C
Density
3.1822
Solubility
Soluble in water, alcohol, ether, carbon disulfide
Safety Information
Risk Statements
21/22-34
TSCA Listed
是
GHS Precautionary statements
P280-P303+P361+P353-P305+P351+P338-P310
RTECS
NN1650000
Hazard Class
8
European Hazard Symbols
Corrosive (C)
Harmful (X)Safety Statements
26-36/37/39-45
GHS Pictograms
Corrosive to metals, category 1
Skin corrosion, categories 1A,1B,1C
Serious eye damage, category 1
Acute toxicity (oral, dermal, inhalation), category 4
Skin irritation, category 2
Eye irritation, category 2
Skin sensitisation, category 1
Specific Target Organ Toxicity – Single exposure, category 3
GHS Hazard statements
H314-H318-H302-H312
Storage Warning
Moisture & Light Sensitive
Packing Group
II
UN Number
UN1792
Molecule Details
No Data Available
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Molecular Spectra
No Data Available
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References
• Reacts with Benzyltrimethylammonium chloride, A16759 to form benzyltrimethylammonium dichloroiodide, a useful reagent for the iodination of phenols: Chem. Lett., 2109 (1987).
• More powerful electrophilic iodinating agent than iodine e.g. for aromatic substitution. For examples of its use in AcOH for aromatic iodination, see: Org. Synth. Coll., 2, 196, 343 (1943).
• The 1:1 complex with pyridine has been recommended as a mild and efficient iodinating agent for a wide range aromatic compounds: J. Chem. Res., 405 (1994). Condensed polycyclic iodides which cannot readily be prepared by direct iodination methods are formed by reaction of the same complex with the organomercurials: J. Chem. Res. (Synop.), 405 (1995).
• For use in combination with NaN3 for the iodoazidation of an olefin, see: Org. Synth. Coll., 6, 893 (1988).