Substance

ID:740591

Lithium bromide, anhydrous

Names and Identifiers
IUPAC name
lithium(1+) ion bromide
IUPAC Traditional name
lithium(1+) ion bromide
Synonyms
Lithium bromide, anhydrous无水溴化锂
Registration numbers
CAS Number
EC Number
MDL Number
Merck Index
Properties
Product Information
Purity
99% min
Physical Property
Melting Point
550°C
Boiling Point
1265°C
Apperance
Crystalline
Density
3.464
Solubility
Very soluble in water and alcohol. Soluble in methanol, acetone, and glycol. Slightly soluble in pyridine
Safety Information
Safety Statements
26-36/37-60
Storage Warning
Hygroscopic
RTECS
OJ5755000
TSCA Listed
GHS Pictograms
GHS07
Acute toxicity (oral, dermal, inhalation), category 4
Skin irritation, category 2
Eye irritation, category 2
Skin sensitisation, category 1
Specific Target Organ Toxicity – Single exposure, category 3
Risk Statements
22-36/38
GHS Hazard statements
H302-H315-H319
GHS Precautionary statements
P280-P305+P351+P338-P302+P352-P321-P362-P501A
European Hazard Symbols
Harmful Harmful (X)
Molecule Details
No Data Available
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Molecular Spectra
No Data Available
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References
• For use in dehydrohalogenation reactions, see Lithium carbonate, 13418. For use in the Horner-Wadsworth-Emmons olefination reaction, see Lithium chloride, A10531, and Triethylamine, A12646. Catalyzes the solvent-free Knoevenagel condenastion of active methylene compounds with aldehydes and ketones: J. Chem. Soc., Perkin 1, 959 (1996). Chemoselective catalyst for the dithioacetalization of aromatic and ɑ?-unsaturated aldehydes under neutral conditions: Synthesis, 58 (1999). Efficient catalyst for the ring-opening of epoxides by amines at room temperature: Eur. J. Org. Chem., 3597 (2004). For a brief feature on uses in synthesis, see: Synlett, 1197 (2005).