Substance
ID:740192
Names and Identifiers
Synonyms
Iron(III) nitrate nonahydrate硝酸铁(III) 九水合物
IUPAC name
iron(3+) ion nonahydrate trinitrate
IUPAC Traditional name
iron(3+) ion nonahydrate trinitrate
Properties
Physical Property
Boiling Point
125°C dec.
Density
1.684
Melting Point
47°C
Apperance
Crystalline, Contains excess HNO3
Safety Information
RTECS
NO7175000
UN Number
UN1466
GHS Pictograms
Oxidizing gases, category 1
Oxidizing liquids, categories 1,2,3
Acute toxicity (oral, dermal, inhalation), category 4
Skin irritation, category 2
Eye irritation, category 2
Skin sensitisation, category 1
Specific Target Organ Toxicity – Single exposure, category 3
Hazard Class
5.1
Safety Statements
17-26-37-60
European Hazard Symbols
Irritant (Xi)
Oxidising (O)Storage Warning
Moisture Sensitive
TSCA Listed
是
GHS Hazard statements
H272-H315-H319
GHS Precautionary statements
P221-P210-P305+P351+P338-P302+P352-P321-P501A
Risk Statements
8-36/38
Packing Group
III
Product Information
Purity
98+% (metals basis)
Molecule Details
No Data Available
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Molecular Spectra
No Data Available
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References
• On a clay support, cleaves 2,4-dinitrophenylhydrazones: Synthesis, 439 (1985).
• Catalyst for preparation of alkali metal amides from the metals in liquid ammonia (numerous Organic Syntheses references).
• Details have been given for an improved method for preparation of the useful oxidizing agent potassium ferrate(VI) by oxidation with hypochlorite, and subsequent use, supported on Montmorillonite K10 clay, for the selective oxidation of benzyl alcohol or benzylamine to benzaldehyde, thiols to disulfides, aniline to azobenzene and various oximes and hydrazones to the parent ketone: J. Org. Chem., 61, 6360 (1996).
• For use in regioselective mononitration of phenols, see: Tetrahedron, 45, 1415 (1989). The reaction can also be carried out in an ionic liquid: Synth. Commun., 33, 961 (2003).