Substance

ID:739914

Silver tetrafluoroborate

Names and Identifiers
IUPAC Traditional name
silver(1+) ion tetrafluoroborate
IUPAC name
silver(1+) ion tetrafluoroboranuide
Synonyms
Silver tetrafluoroborate四氟硼酸银Tetrafluoroboric acid silver salt
Registration numbers
CAS Number
MDL Number
EC Number
Properties
Physical Property
Melting Point
200°C dec.
Apperance
Crystalline
Safety Information
Safety Statements
26-36/37/39-45-60
Hazard Class
8
European Hazard Symbols
Corrosive Corrosive (C)
Harmful Harmful (X)
GHS Pictograms
GHS05
Corrosive to metals, category 1
Skin corrosion, categories 1A,1B,1C
Serious eye damage, category 1
GHS06
Acute toxicity (oral, dermal, inhalation), categories 1,2,3
UN Number
UN3260
GHS Precautionary statements
P280-P303+P361+P353-P305+P351+P338-P310
Storage Warning
Light Sensitive & Hygroscopic
TSCA Listed
RTECS
ED2875000
GHS Hazard statements
H301-H314-H318
Risk Statements
22-34
Packing Group
II
Product Information
Purity
99%
Molecule Details
No Data Available
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Molecular Spectra
No Data Available
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References
• For use in the preparation of stable, non-hygroscopic, crystalline acylammonium salts, see: J. Org. Chem., 57, 5136 (1992).
• Mediates the oxidative coupling of silylated cyclopropanols to 1,6-diones: J. Am. Chem. Soc., 105, 7192 (1983):
• Silver salt soluble in many organic solvents; useful, e.g. in promotion of the leaving ability of halogens. Promotes the conversion of ɑ-bromo aldehydes and ketones to their ɑ-fluoro equivalents: Tetrahedron Lett., 3357 (1979).
• In the presence of AgBF4, acetals of phenacyl halides undergo rearrangement to esters of arylacetic acids: J. Chem. Soc., Perkin 1, 2575 (1982); compare Silver nitrate, 11414.