Substance
ID:739077
Names and Identifiers
IUPAC name
tri-tert-butylphosphane
IUPAC Traditional name
tri-tert-butylphosphane
Synonyms
三特丁基膦Tri-tert-butylphosphine
Properties
Physical Property
Apperance
Solid
Flash Point
-16°C(-3°F)
Boiling Point
102-103°C/13mm
Melting Point
30°C
Safety Information
TSCA Listed
否
GHS Precautionary statements
P210-P303+P361+P353-P305+P351+P338-P405-P422A-P501A
Risk Statements
17-34
Hazard Class
4.2
GHS Pictograms
Flammable gases, category 1
Flammable aerosols, categories 1,2
Flammable liquids, categories 1,2,3
Self-reactive substances and mixtures, Types B,C,D,E,F
Pyrophoric liquids, category 1
Pyrophoric solids, category 1
Self-heating substances and mixtures
Substances and mixtures, which in contact with water, emit flammable gases, categories 1,2,3
Organic peroxides, Types B,C,D,E,F
Corrosive to metals, category 1
Skin corrosion, categories 1A,1B,1C
Serious eye damage, category 1
UN Number
UN2845
Storage Warning
Air & Moisture Sensitive
Packing Group
I
European Hazard Symbols
Corrosive (C)
Flammable (F)GHS Hazard statements
H250-H252-H314-H318
Safety Statements
26-36/37/39-45
Product Information
Purity
96%
Molecule Details
No Data Available
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Molecular Spectra
No Data Available
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References
• For a brief feature on uses of the reagent in synthesis, see: Synlett, 709 (2005).
• Ligand which has been used in conjunction with Tris(dibenzylideneacetone)dipalladium(0), 12760 in promoting Suzuki cross-coupling reactions of arylboronic acids with aryl and vinyl halides under mild conditions. The system is particularly recommended for coupling reactions with normally unreactive aryl chlorides: J. Am. Chem. Soc., 4070 (2000). The same catalyst system has been found to be effective in the room-temperature cyanation of aryl bromides using zinc cyanide: Synlett, 2237 (2003).
• Efficient catalyst for the trifluoromethylation of aldehydes, ketones, imides and imines with (Trifluoromethyl)trimethylsilane, B20347: Synlett, 267 (2006).