Substance
ID:739005
Names and Identifiers
IUPAC name
bis(chloro(prop-2-en-1-yl)palladium)
IUPAC Traditional name
bis(chloro(prop-2-en-1-yl)palladium)
Synonyms
Allylpalladium(II) chloride dimer烯丙基氯化钯(II)二聚体Bis(allyl)dichlorodipalladium(II)
Registration numbers
CAS Number
MDL Number
Beilstein Number
EC Number
Properties
Physical Property
Solubility
Very soluble in dichloromethane and dichloroethane. Slightly soluble in toluene, insoluble in water
Melting Point
120°C dec.
Apperance
Powder
Safety Information
RTECS
RT3510000
Safety Statements
26-37-60
GHS Hazard statements
H315-H319-H335
European Hazard Symbols
Irritant (Xi)GHS Precautionary statements
P261-P305+P351+P338-P302+P352-P321-P405-P501A
TSCA Listed
否
Storage Warning
Air & Moisture Sensitive
Risk Statements
36/37/38
GHS Pictograms
Acute toxicity (oral, dermal, inhalation), category 4
Skin irritation, category 2
Eye irritation, category 2
Skin sensitisation, category 1
Specific Target Organ Toxicity – Single exposure, category 3
Product Information
Purity
Pd 56.0% min
Molecule Details
No Data Available
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Molecular Spectra
No Data Available
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References
• Used in combination with a chiral diamine to effect displacement of a mesylate with Trimethylsilyl azide, L00173, in the asymmetric synthesis of (+)-pancratistin: J. Am. Chem. Soc., 117, 10143 (1995).
• Reacts with lithium enolates of esters, in the presence of CO and excess TMEDA, to give good yields of ɑ-cyclopropyl esters: Angew. Chem. Int. Ed., 31, 234 (1992).