Substance

ID:737883

2-[N,N-Bis(trifluoromethylsulfonyl)amino]-5-chloropyridine

Names and Identifiers
IUPAC name
N-(5-chloropyridin-2-yl)-1,1,1-trifluoro-N-trifluoromethanesulfonylmethanesulfonamide
IUPAC Traditional name
N-(5-chloropyridin-2-yl)-1,1,1-trifluoro-N-trifluoromethanesulfonylmethanesulfonamide
Synonyms
2-[N,N-Bis(trifluoromethanesulfonyl)amino]-5-chloropyridine2-[N,N-Bis(trifluoromethylsulfonyl)amino]-5-chloropyridineN-(5-Chloro-2-pyridyl)triflimide2-[N,N-双(三氟甲烷烷磺酰)氨基]-5-氯吡啶
Registration numbers
MDL Number
Beilstein Number
EC Number
CAS Number
Properties
Safety Information
GHS Precautionary statements
P261-P305+P351+P338-P302+P352-P321-P405-P501A
Safety Statements
26-37
GHS Pictograms
GHS07
Acute toxicity (oral, dermal, inhalation), category 4
Skin irritation, category 2
Eye irritation, category 2
Skin sensitisation, category 1
Specific Target Organ Toxicity – Single exposure, category 3
European Hazard Symbols
Irritant Irritant (Xi)
GHS Hazard statements
H315-H319-H335
Risk Statements
36/37/38
Storage Warning
Moisture Sensitive
TSCA Listed
Product Information
Purity
99%
Physical Property
Melting Point
44-47°C
Molecule Details
No Data Available
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Molecular Spectra
No Data Available
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References
• Highly reactive triflating agent which converts lithium enolates of ketones to vinyl triflates rapidly at low temperatures: Tetrahedron Lett., 33, 6299 (1992). Used in the total synthesis of (-)-porantheridine: J. Am. Chem. Soc.115, 8851 (1993), and the trans decahydroquinoline alkaloid (+)-219A: J. Org. Chem., 60, 794 (1995).