Substance
ID:737829
Names and Identifiers
IUPAC Traditional name
diethyl(1,1,2,3,3,3-hexafluoropropyl)amine
IUPAC name
diethyl(1,1,2,3,3,3-hexafluoropropyl)amine
Synonyms
N,N-Diethyl-1,1,2,3,3,3-hexafluoropropylamine石川试剂Ishikawa's Reagent
Properties
Physical Property
Density
1.230
Refractive Index
1.3500
Boiling Point
56-57°C/58mm
Flash Point
14°C(57°F)
Safety Information
Packing Group
II
European Hazard Symbols
Corrosive (C)
Flammable (F)TSCA Listed
否
GHS Pictograms
Corrosive to metals, category 1
Skin corrosion, categories 1A,1B,1C
Serious eye damage, category 1
Flammable gases, category 1
Flammable aerosols, categories 1,2
Flammable liquids, categories 1,2,3
Self-reactive substances and mixtures, Types B,C,D,E,F
Pyrophoric liquids, category 1
Pyrophoric solids, category 1
Self-heating substances and mixtures
Substances and mixtures, which in contact with water, emit flammable gases, categories 1,2,3
Organic peroxides, Types B,C,D,E,F
UN Number
UN2924
Hazard Class
3
Safety Statements
16-26-36/37/39-45
GHS Hazard statements
H225-H314-H318
Risk Statements
11-34
GHS Precautionary statements
P210-P241-P303+P361+P353-P305+P351+P338-P405-P501A
Product Information
Purity
90+%
Molecule Details
No Data Available
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Molecular Spectra
No Data Available
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References
• For use in conversion, in ether or THF, of alcohols to alkyl fluorides, see: Bull. Chem. Soc. Jpn., 52, 3377 (1979); J. Fluorine Chem., 31, 135 (1986); 38, 243 (1988). Addition of NaF as a scavenger of the HF liberated in the reaction gives improved results: J. Fluorine Chem., 23, 383 (1983). Carboxylic acids are converted to acyl fluorides: Bull. Chem. Soc. Jpn., 52, 3377 (1979).
• A mixture of N,N-Diethyl-1,1,2,3,3,3-hexafluoropropylamine and N,N-Diethyl-1,2,3,3,3-pentafluoropropenamine, both of which are active fluorinating agents.