Substance
ID:737626
Names and Identifiers
IUPAC name
zinc(2+) ion ditrifluoromethanesulfonate
Synonyms
Zinc trifluoromethanesulfonate三氟甲烷磺酸锌Trifluoromethanesulfonic acid zinc saltZinc triflate
IUPAC Traditional name
zinc(2+) ion ditriflate
Registration numbers
CAS Number
MDL Number
Beilstein Number
EC Number
Properties
Safety Information
Storage Warning
Hygroscopic
Safety Statements
26-36/37/39-45-60
European Hazard Symbols
Corrosive (C)GHS Precautionary statements
P260-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501A
UN Number
UN3261
GHS Pictograms
Corrosive to metals, category 1
Skin corrosion, categories 1A,1B,1C
Serious eye damage, category 1
Hazard Class
8
Packing Group
III
GHS Hazard statements
H314-H318
TSCA Listed
是
Risk Statements
34
Physical Property
Melting Point
>300°C
Product Information
Purity
98%
Molecule Details
No Data Available
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Molecular Spectra
No Data Available
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References
• In combination with N-methylephedrine, catalyzes enantioselective addition of terminal alkynes to aldehydes to give propargylic alcohols in high yield and ee: J. Am. Chem. Soc., 122, 1806 (2000).
• Promotes the aldol reaction of silyl enol ethers with aldehydes: Gazz. Chim. Ital., 123, 673 (1993).
• Useful, alone or in combination with TMS chloride, for glycosidation reactions: Chem. Pharm. Bull., 40, 2909 (1992); 41, 201 (1993); 42, 1808 (1994).
• Mild Lewis acid catalyst which promotes thioketalization, particularly of acid-sensitive substrates, with ethanedithiol: Tetrahedron Lett., 24, 169 (1983); J. Am. Chem. Soc., 105, 1662 (1983).