Substance
ID:737311
Names and Identifiers
Synonyms
1-Chloroethyl chloroformate1-氯乙基氯甲酸酯Chloroformic Acid 1-Chloroethyl Ester
IUPAC name
1-chloroethyl chloroformate
IUPAC Traditional name
1-chloroethyl chloroformate
Registration numbers
MDL Number
CAS Number
EC Number
Beilstein Number
Properties
Physical Property
Density
1.312
Flash Point
45°C(113°F)
Boiling Point
119-121°C
Refractive Index
1.4230
Melting Point
-65°C
Safety Information
Hazard Class
6.1
Packing Group
II
GHS Pictograms
Corrosive to metals, category 1
Skin corrosion, categories 1A,1B,1C
Serious eye damage, category 1
Flammable gases, category 1
Flammable aerosols, categories 1,2
Flammable liquids, categories 1,2,3
Self-reactive substances and mixtures, Types B,C,D,E,F
Pyrophoric liquids, category 1
Pyrophoric solids, category 1
Self-heating substances and mixtures
Substances and mixtures, which in contact with water, emit flammable gases, categories 1,2,3
Organic peroxides, Types B,C,D,E,F
Acute toxicity (oral, dermal, inhalation), categories 1,2,3
Risk Statements
10-22-23-34
Safety Statements
26-36/37/39-45
GHS Precautionary statements
P210-P303+P361+P353-P304+P340-P305+P351+P338-P320-P330-P405-P501A
Storage Warning
Moisture Sensitive
GHS Hazard statements
H330-H302-H314-H318-H226
European Hazard Symbols
Toxic (T)TSCA Listed
否
UN Number
UN2742
Product Information
Purity
98%
Molecule Details
No Data Available
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Molecular Spectra
No Data Available
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References
• Reagent, introduced by Olofson, and found to be superior to other chloroformates for dealkylation of tert-amines, e.g. N-alkylpiperidines to piperidines: J. Org. Chem., 49, 2081, 2795, 2081 (1984). For selective debenzylation of tert-amines, see: Synlett, 195 (1993). For reviews, see: Pure Appl. Chem., 60, 1715 (1988); Synthesis, 1 (1989).