Substance

ID:737227

Borane-tetrahydrofuran complex, 1M soln. in THF, stab. with 5mmol NaBH4

Names and Identifiers
IUPAC name
oxolane borane
IUPAC Traditional name
tetrahydrofuran borane
Synonyms
四氢呋喃硼烷,1M 在四氢呋喃溶剂中,以5mmol NaBHBTHFBorane-tetrahydrofuran complex, 1M soln. in THF, stab. with 5mmol NaBH4
Registration numbers
CAS Number
Beilstein Number
MDL Number
EC Number
Properties
Safety Information
Hazard Class
4.3
Packing Group
I
Storage Warning
Air & Moisture Sensitive
GHS Precautionary statements
P210-P231+P232-P303+P361+P353-P305+P351+P338-P405-P501A
UN Number
UN3148
GHS Pictograms
GHS05
Corrosive to metals, category 1
Skin corrosion, categories 1A,1B,1C
Serious eye damage, category 1
GHS07
Acute toxicity (oral, dermal, inhalation), category 4
Skin irritation, category 2
Eye irritation, category 2
Skin sensitisation, category 1
Specific Target Organ Toxicity – Single exposure, category 3
GHS02
Flammable gases, category 1
Flammable aerosols, categories 1,2
Flammable liquids, categories 1,2,3
Self-reactive substances and mixtures, Types B,C,D,E,F
Pyrophoric liquids, category 1
Pyrophoric solids, category 1
Self-heating substances and mixtures
Substances and mixtures, which in contact with water, emit flammable gases, categories 1,2,3
Organic peroxides, Types B,C,D,E,F
GHS08
Respiratory sensitization, category 1
Germ cell mutagenicity, categories 1A,1B,2
Carcinogenicity, categories 1A,1B,2
Reproductive toxicity, categories 1A,1B,2
Specific Target Organ Toxicity – Single exposure, categories 1,2
Specific Target Organ Toxicity – Repeated exposure, categories 1,2
Aspiration Hazard, category 1
GHS Hazard statements
H225-H260-H318-H315-H351-H335-H303
European Hazard Symbols
Irritant Irritant (Xi)
Flammable Flammable (F)
Safety Statements
7/8-9-16-23-26-30-33-36/37/39-43-60
TSCA Listed
Risk Statements
11-14/15-19-37/38-41
Physical Property
Flash Point
-21°C(-8°F)
Density
0.878
Product Information
Concentration
1M soln. in THF
Molecule Details
No Data Available
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Molecular Spectra
No Data Available
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References
• Hydroboration, followed by reaction of the trialkylborane with a diazoketone to give a homologated ketone: Org. Synth. Coll., 6, 919 (1988). In situ generation of "disiamyl" borane from 2-methyl-2-butene, and use of this reagent in selective hydroboration reactions: Org. Synth. Coll., 7, 258 (1990). Preparation of di-3-pinanylborane from (-)-ɑ-pinene, and its use in asymmetric hydroborations, see: Org. Synth. Coll., 7,339 (1990).
• Examples of hydroboration reactions:
• For use in the reduction of carboxylic acids to alcohols, see: Org. Synth. Coll., 7, 221 (1990).
• For other reactions of borane, see Borane-dimethyl sulfide complex, L07705.