Substance
ID:737215
Names and Identifiers
IUPAC name
3-methylbutyl nitrite
Synonyms
Isoamyl nitriteIsopentyl nitrite亚硝酸异戊酯Amyl nitrite
IUPAC Traditional name
aspiral
Registration numbers
CAS Number
MDL Number
EC Number
Beilstein Number
Merck Index
Properties
Physical Property
Boiling Point
95-100°C
Flash Point
-20°C(-4°F)
Refractive Index
1.3870
Density
0.875
Safety Information
Safety Statements
16-24-46
Storage Warning
Air & Light Sensitive
European Hazard Symbols
Harmful (X)
Flammable (F)GHS Pictograms
Acute toxicity (oral, dermal, inhalation), categories 1,2,3
Flammable gases, category 1
Flammable aerosols, categories 1,2
Flammable liquids, categories 1,2,3
Self-reactive substances and mixtures, Types B,C,D,E,F
Pyrophoric liquids, category 1
Pyrophoric solids, category 1
Self-heating substances and mixtures
Substances and mixtures, which in contact with water, emit flammable gases, categories 1,2,3
Organic peroxides, Types B,C,D,E,F
GHS Precautionary statements
P210-P241-P303+P361+P353-P321-P405-P501A
RTECS
NT0187500
GHS Hazard statements
H225-H331-H302
Risk Statements
11-20/22
TSCA Listed
是
UN Number
UN1113
Hazard Class
3
Packing Group
II
Product Information
Purity
97%, stab. with 0.2% anhyd. sodium carbonate
Molecule Details
No Data Available
Click here to submit data
Molecular Spectra
No Data Available
Click here to submit data
References
• For aromatic arylation as an alternative to the Gomberg reaction, see: J. Chem. Soc., 4257 (1962). For deamination of arylamines using THF as a hydrogen donor, see: J. Chem. Soc., Perkin 1, 541 (1973).
• ɑ-Amino esters are converted to ɑ-diazo esters: Tetrahedron, 31, 227 (1975).
• For other reactions of alkyl nitrites, see Isobutyl nitrite, L05259, and tert-Butyl nitrite, L16135.
• Widely used in non-aqueous nitrosation and diazotization reactions.
• For use in the generation of benzyne from anthranilic acid, see: J. Org. Chem., 38, 3462 (1973).