Substance
ID:737066
Names and Identifiers
IUPAC Traditional name
(8aS)-8a-methyl-3,4,7,8-tetrahydro-2H-naphthalene-1,6-dione
IUPAC name
(8aS)-8a-methyl-1,2,3,4,6,7,8,8a-octahydronaphthalene-1,6-dione
Synonyms
(S)-(+)-3,4,8,8a-Tetrahydro-8a-methyl-1,6(2H,7H)-naphthalenedione(S)-Wieland-Miescher ketone(S)-(+)-3,4,8,8a-四氢-8a-甲基-1,6-(2H,7H)-萘二酮(S)-(+)-9-Methyl-Δ(5,10)-octalin-1,6-dione
Properties
Physical Property
Melting Point
48-52°C
Optical Rotation
+100 (c=1 in benzene)
Safety Information
TSCA Listed
否
Product Information
Purity
99%
Molecule Details
No Data Available
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Molecular Spectra
No Data Available
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References
• For an example of use in synthesis of a diterpene, see: J. Chem. Soc., Perkin 1, 2151 (1986), and of taxane intermediates: J. Org. Chem., 57, 3274 (1992).
• Key intermediate in enantioselective steroid syntheses; see, e.g.: Angew. Chem. Int. Ed., 10, 496 (1971); Chem. Ber., 106, 3636 (1973); J. Org. Chem., 45, 2204 (1980).