Substance
ID:736969
Names and Identifiers
IUPAC name
(1S,2S)-1,2-diphenylethane-1,2-diamine
IUPAC Traditional name
diphenylethylenediamine
Synonyms
(1S,2S)-(-)-1,2-Diamino-1,2-diphenylethane(1S,2S)-(-)-1,2-Diphenylethylenediamine(1S,2S)-(+)-1,2-二苯基-1,2-乙二胺(1S,2S)-(-)-1,2-Diphenyl-1,2-ethanediamine
Properties
Physical Property
Optical Rotation
-102 (c=1 in methanol)
Melting Point
80-84°C
Safety Information
GHS Pictograms
Corrosive to metals, category 1
Skin corrosion, categories 1A,1B,1C
Serious eye damage, category 1
Risk Statements
34
GHS Precautionary statements
P280-P305+P351+P338-P309-P310
Safety Statements
26-36/37/39-45
TSCA Listed
否
UN Number
UN3259
Packing Group
III
European Hazard Symbols
Corrosive (C)Storage Warning
Air Sensitive
Hazard Class
8
GHS Hazard statements
H314-H318
Product Information
Purity
97%
Molecule Details
No Data Available
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Molecular Spectra
No Data Available
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References
• Chiral auxiliary and solvation agent; see preceding entry.
• Co-catalyst in the Ru catalyzed enantioselective hydrogenation of aromatic ketones: J. Am. Chem. Soc., 117, 2675 (1995).
• For synthesis of enantiopure ethylenediamines by chirality transfer (condensation with diketones followed by reductive cleavage), see: J. Org. Chem ., 57, 6653 (1992).