Substance
ID:736954
Names and Identifiers
IUPAC name
dimethyl-2,5-dihydrofuran-2,5-dione
IUPAC Traditional name
2,5-furandione, 3,4-dimethyl-
Synonyms
2,3-Dimethylmaleic anhydride3,4-Dimethyl-2,5-furandione2,3-二甲基马来酸 酐
Registration numbers
MDL Number
CAS Number
Beilstein Number
EC Number
Properties
Safety Information
Safety Statements
26-37
TSCA Listed
是
GHS Pictograms
Acute toxicity (oral, dermal, inhalation), category 4
Skin irritation, category 2
Eye irritation, category 2
Skin sensitisation, category 1
Specific Target Organ Toxicity – Single exposure, category 3
GHS Precautionary statements
P261-P305+P351+P338-P302+P352-P321-P405-P501A
Risk Statements
36/37/38
Storage Warning
Moisture Sensitive
European Hazard Symbols
Irritant (Xi)RTECS
ON4025000
GHS Hazard statements
H315-H319-H335
Physical Property
Melting Point
93-96°C
Boiling Point
222-223°C
Product Information
Purity
97%
Molecule Details
No Data Available
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Molecular Spectra
No Data Available
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References
• Does not undergo Diels-Alder reactions with furan, but does react with 1,3-Diphenylisobenzofuran, L00101, to give benzocantharadin: J. Org. Chem., 47, 4011 (1982).
• The use of the dimethylmaleoyl (DMM) group has been investigated for amino group protection in oligosaccharide synthesis. The DMM group is introduced using triethylamine as base. It promotes ? -linkage by neighboring group participation and is stable to acids and non-nucleophilic bases. Cleavage can be brought about by treatment with dilute aqueous NaOH: Eur. J. Org. Chem., 2305 (1998).