Substance

ID:736325

Hexafluoroacetone trihydrate

Names and Identifiers
IUPAC Traditional name
hexafluoroacetone
IUPAC name
hexafluoropropan-2-one
Synonyms
六氟丙酮 三水合物Hexafluoroacetone trihydrate
Registration numbers
Beilstein Number
EC Number
MDL Number
CAS Number
Properties
Physical Property
Boiling Point
105-106°C
Density
1.579
Melting Point
18-21°C
Refractive Index
1.3190
Safety Information
Risk Statements
23/24/25-37/38-41-63
GHS Pictograms
GHS06
Acute toxicity (oral, dermal, inhalation), categories 1,2,3
GHS05
Corrosive to metals, category 1
Skin corrosion, categories 1A,1B,1C
Serious eye damage, category 1
GHS08
Respiratory sensitization, category 1
Germ cell mutagenicity, categories 1A,1B,2
Carcinogenicity, categories 1A,1B,2
Reproductive toxicity, categories 1A,1B,2
Specific Target Organ Toxicity – Single exposure, categories 1,2
Specific Target Organ Toxicity – Repeated exposure, categories 1,2
Aspiration Hazard, category 1
GHS Precautionary statements
P260-P301+P310-P304+P340-P305+P351+P338-P320-P330-P361-P405-P501A
TSCA Listed
GHS Hazard statements
H301-H310-H330-H315-H335-H318-H361
Safety Statements
4-9-20-26-27-36/37/39-45
RTECS
UC2700000
European Hazard Symbols
Toxic Toxic (T)
Packing Group
II
Hazard Class
6.1
UN Number
UN2552
Product Information
Purity
98%
Molecule Details
No Data Available
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Molecular Spectra
No Data Available
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References
• A useful method for epoxidation of alkenes with hydrogen peroxide in the presence of a catalytic amount (ca 1-5 mol%) of hexafluoroacetone trihydrate has been reported by R. A. Sheldon. In chloroform or DCM, reaction is relatively slow and yields moderate; with 1,1,1,3,3,3-Hexafluoro-2-propanol, A12747, as reaction medium, excellent yields of epoxides are obtained after a few hours at room temperature: Synlett, 1305 (2001).