Substance
ID:734090
Names and Identifiers
IUPAC name
triphenylstannane
Synonyms
Triphenyltin hydrideTriphenylstannane三苯基氢化锡
IUPAC Traditional name
triphenyltin hydride
Registration numbers
CAS Number
EC Number
MDL Number
Beilstein Number
Properties
Product Information
Purity
97%
Physical Property
Boiling Point
162-168°C/0.5mm
Density
1.374
Melting Point
26-28°C
Refractive Index
1.6370
Flash Point
>110°C(230°F)
Safety Information
Safety Statements
26-27/28-45-60-61
GHS Hazard statements
H301-H311-H331-H400-H410
Storage Warning
Air & Moisture Sensitive
Packing Group
III
GHS Pictograms
Acute toxicity (oral, dermal, inhalation), categories 1,2,3
Hazardous to the aquatic environment
Acute hazard, category1
Chronic hazard, categories 1,2
GHS Precautionary statements
P280H-P303+P361+P353-P305+P351+P338-P309-P310-P501A
Risk Statements
23/24/25-50/53
TSCA Listed
否
European Hazard Symbols
Toxic (T)
Nature polluting (N)RTECS
WH8882000
UN Number
UN3146
Hazard Class
6.1
Molecule Details
No Data Available
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Molecular Spectra
No Data Available
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References
• Reagent for free-radical desulfurization of the thionocarbonates of 1,2-diols to the corresponding methylenedioxy compounds: J. Org. Chem., 62, 1690 (1997).
• 2-(Bromomethyl)penicillin V methyl ester undergoes ring-expansion via the methylene radical, to give the corresponding cepham: Tetrahedron, 44, 5953 (1988):
• Hydrostannylation of terminal alkynes is conveniently carried out in the presence of triethylboron. Reaction is faster than with tributyl tin hydride and gives higher yields. Stereoselectivity varies from 69-100% (E): Tetrahedron, 45, 923 (1989):
• For general reactions of organotin hydrides, see Tri-n-butyltin hydride, A13298.