Substance
ID:722177
Names and Identifiers
IUPAC name
3-bromofuran
IUPAC Traditional name
3-bromofuran
Synonyms
3-溴呋喃3-Bromofuran
Registration numbers
CAS Number
Beilstein Number
EC Number
MDL Number
Properties
Safety Information
European Hazard Symbols
Irritant (Xi)
Flammable (F)UN Number
UN1993
Safety Statements
9-16-26-37-60
TSCA Listed
否
Hazard Class
3
Packing Group
II
Risk Statements
11-36/37/38
GHS Precautionary statements
P210-P241-P303+P361+P353-P305+P351+P338-P405-P501A
GHS Pictograms
Acute toxicity (oral, dermal, inhalation), category 4
Skin irritation, category 2
Eye irritation, category 2
Skin sensitisation, category 1
Specific Target Organ Toxicity – Single exposure, category 3
Flammable gases, category 1
Flammable aerosols, categories 1,2
Flammable liquids, categories 1,2,3
Self-reactive substances and mixtures, Types B,C,D,E,F
Pyrophoric liquids, category 1
Pyrophoric solids, category 1
Self-heating substances and mixtures
Substances and mixtures, which in contact with water, emit flammable gases, categories 1,2,3
Organic peroxides, Types B,C,D,E,F
GHS Hazard statements
H225-H315-H319-H335
Physical Property
Boiling Point
102-104°C
Flash Point
3°C(37°F)
Density
1.635
Refractive Index
1.4960
Product Information
Purity
97%, stab. with 0.5% calcium carbonate
Molecule Details
No Data Available
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Molecular Spectra
No Data Available
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References
• Precursor of 3-lithiofuran by treatment with n-BuLi at low temperatures. Isomerization to 2-lithiofuran tends to occur above -40o: Tetrahedron, 46, 1199 (1990). With LDA at -78o, selective 2-lithiation can be achieved to give 3-bromo-2-lithiofuran, which has been used in synthesis of phenethylthiazolylthiourea (PETT) analogues as potential HIV-1 reverse transcriptase inhibitors: J. Med. Chem., 39, 4261 (1996).