Substance
ID:721889
Names and Identifiers
IUPAC Traditional name
1,2-benzenedimethanol
Synonyms
o-Xylene-alpha,alpha'-diol1,2-Benzenedimethanol1,2-Bis(hydroxymethyl)benzene邻苯二甲醇
IUPAC name
[2-(hydroxymethyl)phenyl]methanol
Registration numbers
EC Number
MDL Number
CAS Number
Beilstein Number
Properties
Product Information
Purity
97%
Safety Information
TSCA Listed
是
Physical Property
Melting Point
59-64°C
Molecule Details
No Data Available
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Molecular Spectra
No Data Available
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References
• The 7-membered cyclic orthoformates, formed with triethyl or trimethyl orthoformate, are superior reagents for the protection of carbonyl groups as their 2,4-benzodioxepine derivatives. These can be readily cleaved in high yield by Pd-catalyzed hydrogenolysis: Tetrahedron Lett., 30, 4165 (1989); J. Am. Chem. Soc., 116, 558 (1994).
• Has also been employed for the protection of boronic acids, by reaction in THF in the presence of a dehydrating agent, e.g. Na2SO4. These derivatives can be readily cleaved by hydrogenolysis or hydrolysis: Tetrahedron Lett., 37, 6705 (1996).