Substance
ID:721435
Names and Identifiers
IUPAC name
2-(phenylsulfanyl)acetic acid
Synonyms
Thiophenoxyacetic acid(Phenylmercapto)acetic acid(Phenylthio)acetic acid(苯硫基)乙酸
IUPAC Traditional name
phenylthio-acetic acid
Registration numbers
EC Number
CAS Number
MDL Number
Beilstein Number
Properties
Safety Information
Safety Statements
26-37
Risk Statements
36/37/38
GHS Hazard statements
H315-H319-H335
European Hazard Symbols
Irritant (Xi)GHS Pictograms
Acute toxicity (oral, dermal, inhalation), category 4
Skin irritation, category 2
Eye irritation, category 2
Skin sensitisation, category 1
Specific Target Organ Toxicity – Single exposure, category 3
GHS Precautionary statements
P261-P305+P351+P338-P302+P352-P321-P405-P501A
TSCA Listed
否
Product Information
Purity
97%
Physical Property
Melting Point
61-66°C
Molecule Details
No Data Available
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Molecular Spectra
No Data Available
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References
• The dilithio-derivative can be ɑ-monoalkylated in high yield, and the process repeated to give the dialkyl derivative: J. Chem. Soc., Chem. Commun., 714 (1975). Reaction of the dianion with terminal epoxides gives -hydroxy acids which can be cyclized to ɑ-phenylthio--lactones. These can desulfurized with Raney nickel: J. Am. Chem. Soc., 108, 5352 (1986), or oxidatively, leading to butenolides: Chem. Lett., 385 (1974).