Substance
ID:720832
Names and Identifiers
IUPAC Traditional name
1,1,1,3,3,3-hexafluoro-2-phenylpropan-2-ol
IUPAC name
1,1,1,3,3,3-hexafluoro-2-phenylpropan-2-ol
Synonyms
1,1,1,3,3,3-Hexafluoro-2-phenyl-2-propanolHexafluorocumyl alcoholalpha,alpha-Bis(trifluoromethyl)benzyl alcohol1,1,1,3,3,3-六氟代-2-苯基-2-丙醇
Registration numbers
EC Number
MDL Number
CAS Number
Beilstein Number
Properties
Safety Information
TSCA Listed
是
Safety Statements
26-37
GHS Precautionary statements
P210-P241-P303+P361+P353-P305+P351+P338-P405-P501A
Packing Group
III
GHS Hazard statements
H226-H315-H319-H335
European Hazard Symbols
Irritant (Xi)GHS Pictograms
Flammable gases, category 1
Flammable aerosols, categories 1,2
Flammable liquids, categories 1,2,3
Self-reactive substances and mixtures, Types B,C,D,E,F
Pyrophoric liquids, category 1
Pyrophoric solids, category 1
Self-heating substances and mixtures
Substances and mixtures, which in contact with water, emit flammable gases, categories 1,2,3
Organic peroxides, Types B,C,D,E,F
Acute toxicity (oral, dermal, inhalation), category 4
Skin irritation, category 2
Eye irritation, category 2
Skin sensitisation, category 1
Specific Target Organ Toxicity – Single exposure, category 3
Risk Statements
36/37/38
Hazard Class
3
UN Number
UN1987
Physical Property
Boiling Point
159-160°C
Density
1.450
Flash Point
60°C(140°F)
Refractive Index
1.4150
Product Information
Purity
98+%
Molecule Details
No Data Available
Click here to submit data
Molecular Spectra
No Data Available
Click here to submit data
References
• Protection of primary and secondary alcohols as hexafluorophenylisopropyl (HIP) ethers can be effected under Mitsunobu conditions. The HIP group shows outstanding chemical resistance under a wide pH range and also in the presence of nucleophiles, organometallic reagents, oxidants, reducing agents and Lewis acids. Selective deprotection with Li naphthalenide is effective, even at -78o: J. Am. Chem. Soc., 116, 8354 (1994).