Substance
ID:719211
Names and Identifiers
IUPAC name
octadecafluoro-decahydronaphthalene
IUPAC Traditional name
perfluorodecalin
Synonyms
Octadecafluoro(decahydronaphthalene)OctadecafluorodecalinPerfluoro(decahydronaphthalene), cis + trans全氟(十氢化萘),顺式+反式
Registration numbers
CAS Number
MDL Number
EC Number
Beilstein Number
Merck Index
Properties
Physical Property
Density
1.940
Refractive Index
1.3145
Boiling Point
141-142°C
Melting Point
-10 to -7°C
Safety Information
RTECS
QJ3175000
TSCA Listed
是
Product Information
Purity
95%
Molecule Details
No Data Available
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Molecular Spectra
No Data Available
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References
• The ability of perfluorinated solvents to solubilize gases, together with their unique phase properties, have been exploited in a system for oxidation of aldehydes to acids, sulfides to sulfoxides and sulfones, and alkenes to epoxides. The reactions are carried out in the presence of dissolved O2, using a transition metal (Ru, Ni) catalyst with perfluorinated ligands, in a perfluoro(decahydronaphthalene)/toluene solvent mixture under monophasic conditions at 64oC. On cooling, phase separation takes place, enabling the product to be isolated from the toluene phase, and the catalyst system to be recycled in the fluorous phase: Angew. Chem. Int. Ed., 36, 1454 (1997).