Substance
ID:718196
Names and Identifiers
IUPAC name
(cyclohex-1-en-1-yloxy)trimethylsilane
IUPAC Traditional name
(cyclohex-1-en-1-yloxy)trimethylsilane
Synonyms
1-(Trimethylsiloxy)cyclohexene1-Cyclohexenyloxytrimethylsilane1-(三甲基硅氧烷)环己烯
Registration numbers
EC Number
CAS Number
MDL Number
Beilstein Number
Properties
Physical Property
Flash Point
42°C(107°F)
Density
0.883
Refractive Index
1.4470
Boiling Point
165°C
Safety Information
GHS Pictograms
Flammable gases, category 1
Flammable aerosols, categories 1,2
Flammable liquids, categories 1,2,3
Self-reactive substances and mixtures, Types B,C,D,E,F
Pyrophoric liquids, category 1
Pyrophoric solids, category 1
Self-heating substances and mixtures
Substances and mixtures, which in contact with water, emit flammable gases, categories 1,2,3
Organic peroxides, Types B,C,D,E,F
UN Number
UN1993
Packing Group
III
Hazard Class
3
GHS Hazard statements
H226-H303
GHS Precautionary statements
P210-P241-P280-P303+P361+P353-P403+P235-P501A
Risk Statements
10
Storage Warning
Moisture Sensitive
TSCA Listed
是
Product Information
Purity
98%
Molecule Details
No Data Available
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Molecular Spectra
No Data Available
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References
• Condensation with aldehydes is also promoted by F-, particularly TBAF: J. Org. Chem., 48, 932 (1983).
• Silyl enol ethers undergo crossed aldol condensations with aldehydes and ketones: J. Am. Chem. Soc., 96, 7503 (1974); for tabulated results, see: Org. Synth. Coll., 8, 323 (1993):
• The Lewis acid-catalyzed condensation with nitroalkenes leads to 1,4-diketones: J. Am. Chem. Soc., 98, 4679 (1976); Org. Synth. Coll, 7, 414 (1990).
• For reviews of the chemistry of silyl enol ethers, see: Synthesis, 91 (1977); 85 (1983).