Substance
ID:717766
Names and Identifiers
IUPAC name
tetrabutylazanium iodide
IUPAC Traditional name
tetrabutylammonium iodide
Synonyms
Tetra-n-butylammonium iodide四正丁基碘化铵
Registration numbers
EC Number
CAS Number
Beilstein Number
MDL Number
Properties
Physical Property
Melting Point
142-148°C
Safety Information
GHS Hazard statements
H301-H315-H319-H335
GHS Precautionary statements
P261-P301+P310-P305+P351+P338-P302+P352-P405-P501A
GHS Pictograms
Acute toxicity (oral, dermal, inhalation), categories 1,2,3
Risk Statements
22-36/37/38
TSCA Listed
是
RTECS
BS5450000
Storage Warning
Light Sensitive & Hygroscopic
Safety Statements
26-36/37
European Hazard Symbols
Harmful (X)Product Information
Purity
98%
Molecule Details
No Data Available
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Molecular Spectra
No Data Available
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References
• Useful source of I- for nucleophilic displacements, e.g. in the formation of neopentyl iodides from the triflates: J. Org. Chem., 45, 4387 (1980).
• Aliphatic and aromatic sulfonic acids are reduced to thiols in the presence of trifluoroacetic anhydride, followed by hydrolysis of the resulting trifluoroacetates: Tetrahedron Lett., 21, 1235 (1980).
• Catalyst for the high-yield methylation of alcohols with dimethyl sulfate: Angew. Chem., 85, 868; Angew. Chem. Int. Ed., 12, 846 (1973), or the benzylation of alcohols with benzyl bromide in organic solvents: Org. Synth. Coll., 8, 34 (1993); 9, 52 (1998).
• In combination with Boron trifluoride diethyl etherate, A15275, has been used in a mild, versatile cleavage of ethers: Synthesis, 274 (1985).