Substance
ID:717404
Names and Identifiers
IUPAC name
3-bromo-1,1,1-trifluoropropan-2-one
IUPAC Traditional name
3-bromo-1,1,1-trifluoropropan-2-one
Synonyms
1-Bromo-3,3,3-trifluoro-2-propanone1-Bromo-3,3,3-trifluoroacetone1-溴-3,33-Bromo-1,1,1-trifluoroacetone
Registration numbers
CAS Number
Beilstein Number
MDL Number
EC Number
Properties
Safety Information
GHS Precautionary statements
P210-P241-P303+P361+P353-P305+P351+P338-P405-P501A
TSCA Listed
否
GHS Pictograms
Flammable gases, category 1
Flammable aerosols, categories 1,2
Flammable liquids, categories 1,2,3
Self-reactive substances and mixtures, Types B,C,D,E,F
Pyrophoric liquids, category 1
Pyrophoric solids, category 1
Self-heating substances and mixtures
Substances and mixtures, which in contact with water, emit flammable gases, categories 1,2,3
Organic peroxides, Types B,C,D,E,F
Corrosive to metals, category 1
Skin corrosion, categories 1A,1B,1C
Serious eye damage, category 1
Hazard Class
3
GHS Hazard statements
H225-H314-H318
European Hazard Symbols
Corrosive (C)
Flammable (F)UN Number
UN2924
Packing Group
II
Risk Statements
11-34
Safety Statements
9-16-26-36/37/39-45
Physical Property
Flash Point
-2°C(28°F)
Melting Point
<-80°C
Density
1.822
Refractive Index
1.3760
Boiling Point
85-87°C
Product Information
Purity
97%
Molecule Details
No Data Available
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Molecular Spectra
No Data Available
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References
• The oxime is readily converted with base to the highly reactive species 1,1,1-trifluoro-2-nitroso-2-propene, which undergoes hetero-Diels-Alder reactions, e.g. with cyclopentadiene or indole to give fused oxazolines. The indole adduct rearomatizes to give 1-(3-indolyl)-3,3,3-trifluoroacetoxime: J. Org. Chem., 57, 339 (1992).
• A novel reductive olefination reaction with aldehydes, mediated by Ti(O-i-Pr)4 and PPh3, provides a one-pot synthesis of trifluoromethylated trans-allylic alcohols: Chem. Commun., 2195 (1998):
