Substance
ID:717076
Names and Identifiers
IUPAC name
hydrogen bromide
IUPAC Traditional name
hydrogen bromide
Synonyms
氢溴酸Hydrogen bromideHydrobromic acid acetic acid solution
Registration numbers
CAS Number
EC Number
Beilstein Number
MDL Number
Merck Index
Properties
Safety Information
European Hazard Symbols
Corrosive (C)Safety Statements
26-36/37/39-45
TSCA Listed
是
Hazard Class
8
Packing Group
II
GHS Pictograms
Acute toxicity (oral, dermal, inhalation), categories 1,2,3
Corrosive to metals, category 1
Skin corrosion, categories 1A,1B,1C
Serious eye damage, category 1
GHS Hazard statements
H331-H314-H318-H227
UN Number
UN3265
GHS Precautionary statements
P280-P305+P351+P338-P309-P310
RTECS
MW3850000
Risk Statements
35
Physical Property
Density
1.40
Flash Point
65°C(149°F)
Product Information
Purity
33% w/w (45% w/v) soln. in acetic acid
Molecule Details
No Data Available
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Molecular Spectra
No Data Available
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References
• For use in the bromoacetoxylation of (S)-(+)-1,2-Propanediol, B21773, as an example of the conversion of chiral vic-diols to epoxides with retention of configuration, see: J. Chem. Soc., Perkin 1, 1214 (1973); Org. Synth. Coll., 7, 356 (1990).
• Preferred reagent for the non-hydrogenolytic cleavage of the N-benzyloxycarbonyl (Cbz, Z) group in peptide synthesis: J. Org. Chem., 17, 1564 (1952). For peptide reagents, see Appendix 6.
• Used in combination with Paraformaldehyde, A11313, or 1,3,5-Trioxane, A15639, for the bromomethylation of aromatics: J. Org. Chem., 58, 1262 (1993); Synlett, 55 (1989). For N-bromomethylation of phthalimide and other imides, see: Synlett, 933 (1994).