Substance

ID:716906

Chlorodiphenylphosphine

Names and Identifiers
Synonyms
Diphenylphosphinous chlorideChlorodiphenylphosphineDiphenyl chlorophosphine二苯基氯化膦
IUPAC Traditional name
chlorodiphenylphosphine
IUPAC name
chlorodiphenylphosphane
Registration numbers
CAS Number
Beilstein Number
EC Number
MDL Number
Properties
Physical Property
Density
1.204
Refractive Index
1.6350
Melting Point
14-16°C
Boiling Point
318-321°C
Flash Point
138°C(280°F)
Safety Information
GHS Pictograms
GHS05
Corrosive to metals, category 1
Skin corrosion, categories 1A,1B,1C
Serious eye damage, category 1
GHS06
Acute toxicity (oral, dermal, inhalation), categories 1,2,3
European Hazard Symbols
Harmful Harmful (X)
Corrosive Corrosive (C)
UN Number
UN3265
GHS Hazard statements
H301-H314-H318
GHS Precautionary statements
P280-P303+P361+P353-P305+P351+P338-P310-P402
Safety Statements
26-36/37/39-45
Storage Warning
Air & Moisture Sensitive
Packing Group
II
TSCA Listed
Hazard Class
8
Risk Statements
14-22-34
Product Information
Purity
97%
Molecule Details
No Data Available
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Molecular Spectra
No Data Available
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References
• Reacts with Li metal in liquid ammonia to give the Li diphenylphosphide: Tetrahedron Lett., 21, 3535 (1980). Reaction with vinyl lithium intermediates from the reaction of alkyllithiums with sulfonylhydrazones (see p-Toluenesulfonyl hydrazide, A13529) gives vinylphosphines: Tetrahedron Lett., 22, 4619 (1981).