Substance

ID:716768

Names and Identifiers
IUPAC name
4-methylquinoline
IUPAC Traditional name
4-methylquinoline
Synonyms
4-Methylquinoline勒皮啶Lepidine
Registration numbers
EC Number
CAS Number
MDL Number
Beilstein Number
Merck Index
Properties
Product Information
Purity
98%
Safety Information
European Hazard Symbols
Irritant Irritant (Xi)
Storage Warning
Light Sensitive
Risk Statements
36/38-68
GHS Precautionary statements
P280-P305+P351+P338-P302+P352-P321-P405-P501A
TSCA Listed
GHS Pictograms
GHS07
Acute toxicity (oral, dermal, inhalation), category 4
Skin irritation, category 2
Eye irritation, category 2
Skin sensitisation, category 1
Specific Target Organ Toxicity – Single exposure, category 3
GHS08
Respiratory sensitization, category 1
Germ cell mutagenicity, categories 1A,1B,2
Carcinogenicity, categories 1A,1B,2
Reproductive toxicity, categories 1A,1B,2
Specific Target Organ Toxicity – Single exposure, categories 1,2
Specific Target Organ Toxicity – Repeated exposure, categories 1,2
Aspiration Hazard, category 1
GHS Hazard statements
H341-H315-H319
RTECS
OH0316000
Safety Statements
23-26-36/37
Physical Property
Refractive Index
1.6200
Flash Point
>110°C(230°F)
Boiling Point
260-263°C
Density
1.083
Melting Point
9-10°C
Molecule Details
No Data Available
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Molecular Spectra
No Data Available
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References
• Lepidine and similar compounds can be alkylated at the 2-position by free radicals generated by the action of t-butyl hydroperoxide and a salt of Fe(II) on a primary or secondary alkyl iodide: Acta Chem. Scand., 43, 995 (1989). Similarly, 2-formylation can be achieved in high yield using 1,3,5-trioxane in the presence of TFA, t-BuOOH and FeSO4 in acetonitrile: J. Org. Chem., 51, 536 (1986).