Substance

ID:716756

Names and Identifiers
IUPAC name
3-bromothiophene
IUPAC Traditional name
3-bromothiophene
Synonyms
3-Thienyl bromide3-Bromothiophene3-溴噻吩
Registration numbers
Beilstein Number
CAS Number
EC Number
MDL Number
Properties
Product Information
Purity
97%
Safety Information
GHS Hazard statements
H300-H310-H330-H315-H319-H335-H227-H401-H411
TSCA Listed
UN Number
UN2810
GHS Pictograms
GHS09
Hazardous to the aquatic environment
Acute hazard, category1
Chronic hazard, categories 1,2
GHS06
Acute toxicity (oral, dermal, inhalation), categories 1,2,3
GHS Precautionary statements
P210-P301+P310-P304+P340-P305+P351+P338-P320-P330-P361-P405-P501A
Packing Group
II
Risk Statements
23/24/25-36/37/38-51/53
European Hazard Symbols
Nature polluting Nature polluting (N)
Toxic Toxic (T)
Hazard Class
6.1
Safety Statements
26-27-36/37-45-61
Physical Property
Flash Point
63°C(145°F)
Boiling Point
157-158°C
Refractive Index
1.5910
Density
1.722
Molecule Details
No Data Available
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Molecular Spectra
No Data Available
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References
• Intermediate for preparation of 3-substituted thiophenes by the Grignard route: Arkiv. Kemi., 13, 295 (1959). Similarly, used in the synthesis of poly(3-alkylthiophenes) as conducting polymers: J. Org. Chem., 58, 904 (1993). Conditions have been described for the formation of 3-lithiothiophene, previously considered to be stable only under cryogenic conditions. It has been found to be stable in hexane solution at ambient temperature: Tetrahedron Lett., 35, 3673 (1994). Subsequent reaction with electrophiles leads to a variety of 3-substituted thiophenes.