Substance
ID:716698
Names and Identifiers
IUPAC name
eth-1-ene-1,1,2,2-tetracarbonitrile
IUPAC Traditional name
tetracyanoethylene
Synonyms
Tetracyanoethylene四氰基乙烯
Registration numbers
EC Number
MDL Number
Beilstein Number
CAS Number
Merck Index
Properties
Physical Property
Boiling Point
223°C
Density
1.348
Melting Point
197-199°C
Safety Information
Packing Group
II
GHS Pictograms
Acute toxicity (oral, dermal, inhalation), categories 1,2,3
Risk Statements
24-28-36/37/38
TSCA Listed
是
Safety Statements
20-26-27/28-36/37-45
GHS Precautionary statements
P261-P301+P310-P305+P351+P338-P361-P405-P501A
Storage Warning
Moisture Sensitive
European Hazard Symbols
Highly toxic (T+)UN Number
UN3439
RTECS
KM7300000
GHS Hazard statements
H300-H310-H315-H319-H335
Hazard Class
6.1
Product Information
Purity
98%
Molecule Details
No Data Available
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Molecular Spectra
No Data Available
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References
• π-Acid catalyst, compare DDQ (2,3-Dichloro-5,6-dicyanobenzoquinone, A11879) for the rearrangement of epoxides to ketones, formation of acetonides (1,3-dioxolanes) by reaction of epoxides with acetone: Chem. Lett., 17 (1993), formation of epoxides with hydrogen peroxide: Chem. Pharm. Bull., 43, 686 (1995), and for stereospecific alcoholysis of epoxides under mild conditions: Synlett, 847 (1993). In the presence of pyridine, carboxylic acids are converted to anhydrides: Tetrahedron Lett., 26, 1503 (1985). In an alcohol as solvent, catalyzes esterification and transesterification reactions: Chem. Lett., 55 (1997).
• Also catalyzes the carbon-carbon bond formation reactions of aldehydes, ketones and acetals with silylated nucleophiles including Trimethylsilyl cyanide, A19598, allyltrimethylsilane, silyl enol ethers and triethylsilane: J. Chem. Soc., Perkin 1, 2155 (1995).
• Versatile reagent and reactive dienophile. Reviews: Miscellaneous chemistry: Chem. Rev., 67, 611 (1967); Synthesis, 249 (1986); Addition and cycloaddition reactions: Synthesis, 749 (1987); Organometallic chemistry: Synthesis, 959 (1987).