Substance
ID:716548
Names and Identifiers
IUPAC Traditional name
butylboronic acid
IUPAC name
butylboronic acid
Synonyms
正丁基硼酸1-Butylboronic acidn-Butaneboronic Acid
Registration numbers
Beilstein Number
MDL Number
CAS Number
EC Number
Properties
Safety Information
GHS Pictograms
Acute toxicity (oral, dermal, inhalation), category 4
Skin irritation, category 2
Eye irritation, category 2
Skin sensitisation, category 1
Specific Target Organ Toxicity – Single exposure, category 3
Risk Statements
36/37/38
Safety Statements
26-37
European Hazard Symbols
Irritant (Xi)TSCA Listed
否
GHS Hazard statements
H315-H319-H335
GHS Precautionary statements
P261-P305+P351+P338-P302+P352-P321-P405-P501A
Storage Warning
Air Sensitive & Hygroscopic
Product Information
Purity
98%
Physical Property
Melting Point
92-96°C
Molecule Details
No Data Available
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Molecular Spectra
No Data Available
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References
• Reagent for preparation of volatile derivatives of diols, e.g. carbohydrates, for GC and mass spectrometry: J. Chromat., 54, 193 (1971); J. Chromat. Sci., 9, 18 (1971); Gas Chromat., 129 (1968).
• In combination with (S)-(-)-ɑ,ɑ-Diphenylprolinol, L09217, or its enantiomer (9218), oxazaborolidine catalysts are generated in situ, for use in highly enantioselective reductions: Tetrahedron Lett., 33, 4141 (1992). The same system has been employed in the synthesis of chiral monosubstituted oxiranes: Tetrahedron Lett., 34, 5227 (1993). See also (S)-2-Methyl-CBS-oxazaborolidine monohydrate, L09219, and Appendix 5.