Substance
ID:716501
Names and Identifiers
Synonyms
TriiodomethaneIodoform碘仿
IUPAC Traditional name
iodoform
IUPAC name
triiodomethane
Registration numbers
CAS Number
EC Number
Beilstein Number
MDL Number
Merck Index
Properties
Product Information
Purity
99%
Safety Information
GHS Hazard statements
H301-H311-H332-H315-H319-H335
Risk Statements
20/21/22-36/37/38
TSCA Listed
是
Safety Statements
26-36/37
GHS Pictograms
Acute toxicity (oral, dermal, inhalation), categories 1,2,3
European Hazard Symbols
Harmful (X)GHS Precautionary statements
P261-P301+P310-P305+P351+P338-P361-P405-P501A
RTECS
PB7000000
Storage Warning
Light Sensitive
Physical Property
Melting Point
118-123°C
Flash Point
None
Density
4.008
Molecule Details
No Data Available
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Molecular Spectra
No Data Available
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References
• Precursor of diiodocarbene under phase-transfer conditions: Angew. Chem. Int. Ed., 13, 132 (1974), or using KO-t-Bu: Synthesis, 313 (1976). Generation of diiodocarbene with NaH in ether and reaction with malonate is the first step of a route to vinyl iodides: J. Chem. Soc., Perkin 1, 47 (1990):
• In the presence of solid NaOH, free radical iodination of saturated hydrocarbons has been accomplished under mild conditions. The reaction is thought to involve the triiodomethyl radical as a chain carrier: Angew. Chem. Int. Ed., 38, 2786 (1999).