Substance
ID:716045
Names and Identifiers
IUPAC name
2-chloro-2-methylpropane
IUPAC Traditional name
tert-butyl chloride
Synonyms
2-Chloro-2-methylpropanetert-Butyl chloride叔丁基氯
Registration numbers
MDL Number
Merck Index
CAS Number
EC Number
Beilstein Number
Properties
Physical Property
Refractive Index
1.3848
Density
0.846
Melting Point
-26°C
Boiling Point
50-52°C
Flash Point
-27°C(-16°F)
Safety Information
RTECS
TX5040000
European Hazard Symbols
Flammable (F)TSCA Listed
是
UN Number
UN1127
Safety Statements
9-16-29-33
GHS Pictograms
Flammable gases, category 1
Flammable aerosols, categories 1,2
Flammable liquids, categories 1,2,3
Self-reactive substances and mixtures, Types B,C,D,E,F
Pyrophoric liquids, category 1
Pyrophoric solids, category 1
Self-heating substances and mixtures
Substances and mixtures, which in contact with water, emit flammable gases, categories 1,2,3
Organic peroxides, Types B,C,D,E,F
GHS Hazard statements
H225
Risk Statements
11
GHS Precautionary statements
P210-P241-P280-P303+P361+P353-P403+P235-P501A
Hazard Class
3
Packing Group
II
Product Information
Purity
98+%
Molecule Details
No Data Available
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Molecular Spectra
No Data Available
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References
• Alkylation of malonate esters with tertiary halides can be accomplished using AlCl3 in nitromethane, avoiding the competing elimination reaction: Liebigs Ann. Chem., 718, 101 (1968). For alkylation of malononitrile, see: Angew. Chem. Int. Ed., 5, 1044 (1966); Org. Synth. Coll., 6, 223 (1988). For high yield alkylation of TMS enol ethers of ketones by reaction with tert-alkyl halides in the presence of various Lewis acid catalysts, see: Angew. Chem. Int. Ed., 17, 48 (1978); Chem. Ber., 113, 3734 (1980).