Substance

ID:715837

Ethylene chlorophosphite

Names and Identifiers
IUPAC name
2-chloro-1,3,2-dioxaphospholane
IUPAC Traditional name
2-chloro-1,3,2-dioxaphospholane
Synonyms
2-Chloro-1,3,2-dioxaphospholane氯代亚磷酸亚乙酯Ethylene chlorophosphite
Registration numbers
MDL Number
CAS Number
EC Number
Beilstein Number
Properties
Safety Information
European Hazard Symbols
Corrosive Corrosive (C)
Packing Group
II
Storage Warning
Moisture Sensitive
TSCA Listed
GHS Hazard statements
H314-H318-H227
Safety Statements
26-36/37/39-45
Hazard Class
8
GHS Pictograms
GHS05
Corrosive to metals, category 1
Skin corrosion, categories 1A,1B,1C
Serious eye damage, category 1
GHS Precautionary statements
P210-P260-P303+P361+P353-P305+P351+P338-P405-P501A
UN Number
UN3265
Risk Statements
14-34
Physical Property
Flash Point
86°C(186°F)
Refractive Index
1.4910
Density
1.415
Boiling Point
46-47°C/15mm
Product Information
Purity
97%
Molecule Details
No Data Available
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Molecular Spectra
No Data Available
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References
• Used in the coupling of arylamines with CS2 to give diarylthioureas: Rev. Roum. Chim., 29, 329 (1984).
• In conjunction with triethyl phosphite, dehydrates primary carboxamides to nitriles, which has been applied in peptide chemistry: J. Am. Chem. Soc., 88, 2025 (1966).
• Peptide coupling reagent via the mixed anhydride; see Appendix 6: J. Am. Chem. Soc., 72, 5491 (1950).