Substance
ID:715759
Names and Identifiers
IUPAC name
phenyl chloroformate
IUPAC Traditional name
phenyl chloroformate
Synonyms
Chloroformic acid phenyl ester氯甲酸苯酯Phenyl chloroformate
Registration numbers
MDL Number
CAS Number
Beilstein Number
EC Number
Properties
Physical Property
Density
1.246
Boiling Point
188-189°C
Flash Point
76°C(169°F)
Refractive Index
1.5110
Melting Point
-38°C
Safety Information
GHS Pictograms
Corrosive to metals, category 1
Skin corrosion, categories 1A,1B,1C
Serious eye damage, category 1
Acute toxicity (oral, dermal, inhalation), categories 1,2,3
Risk Statements
22-26-34-43
European Hazard Symbols
Highly toxic (T+)Packing Group
II
GHS Precautionary statements
P210-P301+P310-P303+P361+P353-P304+P340-P305+P351+P338-P320-P330-P405-P501A
RTECS
FG3850000
Safety Statements
26-28-36/37/39-45
Storage Warning
Moisture Sensitive
Hazard Class
6.1
GHS Hazard statements
H301-H330-H317-H314-H318-H227
TSCA Listed
是
UN Number
UN2746
Product Information
Purity
99%
Molecule Details
No Data Available
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Molecular Spectra
No Data Available
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References
• Reagent for dehydration of primary amides to nitriles under mild conditions: Indian J. Chem., 40B, 722 (2001).
• Also used in the cleavage of tertiary amines: J. Chem. Soc. (C), 2015 (1967); cf Ethyl chloroformate, L06311, and 1-Chloroethyl chloroformate, L14197. Review: Synthesis, 1 (1989).
• Precursor of phenyl mixed anhydrides, which can be used, e.g. in peptide coupling reactions.