Substance
ID:715759
Names and Identifiers
IUPAC name
phenyl chloroformate
IUPAC Traditional name
phenyl chloroformate
Synonyms
Chloroformic acid phenyl ester氯甲酸苯酯Phenyl chloroformate
Registration numbers
MDL Number
CAS Number
Beilstein Number
EC Number
Properties
Safety Information
GHS Hazard statements
H301-H330-H317-H314-H318-H227
GHS Precautionary statements
P210-P301+P310-P303+P361+P353-P304+P340-P305+P351+P338-P320-P330-P405-P501A
European Hazard Symbols
Highly toxic (T+)GHS Pictograms
Acute toxicity (oral, dermal, inhalation), categories 1,2,3
Corrosive to metals, category 1
Skin corrosion, categories 1A,1B,1C
Serious eye damage, category 1
Risk Statements
22-26-34-43
Storage Warning
Moisture Sensitive
Safety Statements
26-28-36/37/39-45
Hazard Class
6.1
Packing Group
II
UN Number
UN2746
RTECS
FG3850000
TSCA Listed
是
Product Information
Purity
99%
Physical Property
Boiling Point
188-189°C
Flash Point
76°C(169°F)
Melting Point
-38°C
Density
1.246
Refractive Index
1.5110
Molecule Details
No Data Available
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Molecular Spectra
No Data Available
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References
• Also used in the cleavage of tertiary amines: J. Chem. Soc. (C), 2015 (1967); cf Ethyl chloroformate, L06311, and 1-Chloroethyl chloroformate, L14197. Review: Synthesis, 1 (1989).
• Reagent for dehydration of primary amides to nitriles under mild conditions: Indian J. Chem., 40B, 722 (2001).
• Precursor of phenyl mixed anhydrides, which can be used, e.g. in peptide coupling reactions.