Substance
ID:715508
Names and Identifiers
IUPAC name
2-bromo-1,3,5-trimethylbenzene
IUPAC Traditional name
2-bromo-1,3,5-trimethylbenzene
Synonyms
2-Bromo-1,3,5-trimethylbenzene2,4,6-Trimethylbromobenzene2-溴均三甲基苯2-Bromomesitylene
Registration numbers
EC Number
MDL Number
Beilstein Number
CAS Number
Properties
Safety Information
Safety Statements
23-26-37
TSCA Listed
是
GHS Pictograms
Acute toxicity (oral, dermal, inhalation), category 4
Skin irritation, category 2
Eye irritation, category 2
Skin sensitisation, category 1
Specific Target Organ Toxicity – Single exposure, category 3
European Hazard Symbols
Irritant (Xi)Risk Statements
36/37/38
Storage Warning
Light Sensitive
GHS Precautionary statements
P261-P305+P351+P338-P302+P352-P321-P405-P501A
GHS Hazard statements
H315-H319-H335
Physical Property
Refractive Index
1.5520
Boiling Point
224-226°C
Density
1.322
Flash Point
96°C(204°F)
Melting Point
2°C
Product Information
Purity
99%
Molecule Details
No Data Available
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Molecular Spectra
No Data Available
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References
• In the presence of Pd catalysts and a base, aryl bromides can act as oxidizing agents for conversion of alcohols to aldehydes and ketones under mild conditions. While bromobenzene is effective for saturated secondary alcohols: Tetrahedron Lett., 1401 (1979), for unsaturated alcohols, arylation competes and 2-bromomesitylene was found to give superior results: Tetrahedron Lett., 22, 1801 (1981); J. Org. Chem., 48, 1286 (1983). See also: J. Org. Chem., 61, 2918 (1996), for a combined desilylation-oxidation technique.