Substance
ID:715379
Names and Identifiers
Synonyms
Tris(o-tolyl)phosphineTri(o-tolyl)phosphineTris(2-methylphenyl)phosphine三(邻甲苯)膦
IUPAC Traditional name
tris(2-methylphenyl)phosphane
IUPAC name
tris(2-methylphenyl)phosphane
Registration numbers
CAS Number
MDL Number
EC Number
Beilstein Number
Properties
Safety Information
Safety Statements
26-37
GHS Hazard statements
H315-H319-H335
European Hazard Symbols
Irritant (Xi)Risk Statements
36/37/38
TSCA Listed
是
GHS Precautionary statements
P261-P305+P351+P338-P302+P352-P321-P405-P501A
GHS Pictograms
Acute toxicity (oral, dermal, inhalation), category 4
Skin irritation, category 2
Eye irritation, category 2
Skin sensitisation, category 1
Specific Target Organ Toxicity – Single exposure, category 3
Product Information
Purity
98+%
Physical Property
Melting Point
122-127°C
Molecule Details
No Data Available
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Molecular Spectra
No Data Available
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References
• The Pd-catalyzed amination of bromoarenes with 1-Boc-piperazine, L13363, in the presence of this ligand, provides a route to arylpiperazines of potential pharmacological interest: Tetrahedron Lett., 39, 2219 (1998).
• Preferred phosphine ligand for use in combination with Pd salts in the Heck-type coupling reactions of vinylic halides. For examples, see Palladium(II) acetate, 10516. For a review of the Heck reaction, see: Org. React., 27, 345 (1982).